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Gas phase ethylene polymerization over SiO

Liuzhong LI, Aiyou HAO, Ruihua CHENG, Boping LIU

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 1,   Pages 89-95 doi: 10.1007/s11705-010-0558-x

Abstract: Although an important industrial catalyst for producing high density polyethylene, the SiO -supportedorganosilyl chromate UCC S-2 catalyst has not been fully investigated compared with the SiO -supportedoxo chromium Phillips catalyst.The innovation by a simple catalyst technology created a new application to meet market demands.

Keywords: UCC S-2 catalyst     Al-alkyl co-catalyst     gas-phase ethylene polymerization     high density polyethylene    

Dendritic BiVO4 decorated with MnOx co-catalyst as an efficient hierarchical catalyst for photocatalytic

Jin Yang, Xuelian Liu, Hongbin Cao, Yanchun Shi, Yongbing Xie, Jiadong Xiao

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 1,   Pages 185-191 doi: 10.1007/s11705-018-1713-z

Abstract: An appropriate co-catalyst can significantly promote the photocatalytic efficacy, but this has been seldomThis work provides a new direction of catalyst preparation and pushes forward the application of photocatalytic

Keywords: manganese oxide     bismuth vanadium tetraoxide     photocatalytic ozonation     hydroxyl radical     co-catalyst    

Mass Transfer-Promoted Fe2+/Fe3+ Circulation Steered by 3D Flow-Through Co-Catalyst System Toward Sustainable

Weiyang Lv,Hao Li,Jinhui Wang,Lixin Wang,Zenglong Wu,Yuge Wang,Wenkai Song,Wenkai Cheng,Yuyuan Yao,

Engineering doi: 10.1016/j.eng.2023.06.010

Abstract: However, current AOPs assisted by co-catalysts still suffer from the poor mass/electron transfer andHerein, we present a three-dimensional (3D) macroscale co-catalyst functionalized with MoS2co-catalytic system with superwetting capabilities can even tackle the intricateOur findings highlight an innovative co-catalyst system design to expand the applicability of AOPs based

Keywords: Advanced oxidation processes     3D co-catalyst     Flow-through mode     Enhanced mass transfer     Complex wastewater    

Improved Oxygen Evolution Kinetics and Surface States Passivation of Ni-Bi Co-Catalyst for Letter

Ke Dang,Tuo Wang,Chengcheng Li,Jijie Zhang,Shanshan Liu,Jinlong Gong

Engineering 2017, Volume 3, Issue 3,   Pages 285-289 doi: 10.1016/J.ENG.2017.03.005

Abstract: combinational surface kinetics enhancement and surface states passivation of nickel-borate (Ni-Bi) co-catalyst

Keywords: Nickel-borate     Hematite     Oxygen evolution reaction     Co-catalyst    

Effect of alkyl nitrite decomposition on catalytic performance of CO coupling reaction over supportedpalladium catalyst

Zhenhua LI, Weihan WANG, Dongxue YIN, Jing LV, Xinbin MA

Frontiers of Chemical Science and Engineering 2012, Volume 6, Issue 4,   Pages 410-414 doi: 10.1007/s11705-012-1213-5

Abstract: The syntheses of dimethyl oxalate (DMO) and diethyl oxalate (DEO) by CO coupling reaction in gaseousphase were investigated in a fixed bed reactor over Pd-Fe/Al O catalyst.The results showed that over Pd-Fe/Al O catalyst, the STY of DMO was higher than that of DEO under thetemperatures for synthesizing DMO and DEO were 403 K and 393 K, respectively, at the molar ratio 1 ∶ 1 of alkylnitrite to CO.

Keywords: palladium     CO coupling     dialkyl oxalate     alkyl nitrite     decomposition    

Ni-Co bimetallic catalyst for CH

Xiaohong LI, Jun AI, Wenying LI, Dongxiong LI

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 4,   Pages 476-480 doi: 10.1007/s11705-010-0512-y

Abstract: A co-precipitation method was employed to prepare Ni/Al O -ZrO , Co/Al O -ZrO and Ni-Co/Al O -ZrO catalystsNi-Co/Al O -ZrO bimetallic catalyst has good performance in the reduction of active components Ni, CoCompared with mono-metallic catalyst, bimetallic catalyst could provide more active sites and CO adsorptionAccording to the CH -CO -TPSR, there were 80.9% and 81.5% higher CH and CO conversion over Ni-Co/AlThe high activity and excellent anti-coking of the Ni-Co/Al O -ZrO catalyst were closely related to

Keywords: Ni-Co bimetallic catalyst     composite support     CH4 reforming with CO2    

The stabilization effect of Al2O3 on unconventional Pb/SiO2 catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al2O3 with a small amount, wasintroduced into Pb/SiO2 catalyst in this study.As a result, 3Al15Pb/SiO2 catalyst exhibits a much higher stability up to more than 150 h.In addition, a simple schematic diagram of the change of surface species on the catalyst surface afterAl2O3 addition was also proposed.

Keywords: Pb/SiO2     Al2O3     propane dehydrogenation     propene     stability    

The catalytic effect of both oxygen-bearing functional group and ash in carbonaceous catalyst on CH 4-CO 2 reforming

Weidong ZHANG, Yongfa ZHANG,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 2,   Pages 147-152 doi: 10.1007/s11705-009-0242-1

Abstract: A kind of new catalyst—carbonaceous catalyst—for CH-CO reformation has been developed inIt has been found that the carbonaceous catalyst is an efficient catalyst on CO-CH reforming.; the ash components in carbonaceous catalyst also have an important influence on the CO-CH reformingFeO, NaCO, and KCO in the ash can catalyze the CO-CH reforming reaction; CaO has little effect on CO-CHCaO can catalyze the gasification between carbonaceous catalyst and CO; AlO and MgO inhibit the CO-CH

Keywords: oxygen-bearing functional     carboxyl     phenolic hydroxyl     CH-CO reformation     CO-CH reforming    

Resistance to acid degradation, sorptivity, and setting time of geopolymer mortars

Osama A MOHAMED; Rania AL-KHATTAB; Waddah AL-HAWAT

Frontiers of Structural and Civil Engineering 2022, Volume 16, Issue 6,   Pages 781-791 doi: 10.1007/s11709-022-0862-9

Abstract: Experimental evaluations were conducted to determine the water sorptivity, setting time, and resistance to a highly acidic environment, of mortar with alkali-activated ground granulated blast furnace slag (GBS) binder and also of combinations of fly ash and GBS binders. Binders were activated using mixtures of NaOH and Na2SiO3 solutions. The molarity of NaOH in the mixtures ranged from 10 mol·L−1 to 16 mol·L−1, and the Na2SiO3/NaOH ratio was varied from 1.5 to 2.5. Mortar samples were produced using three binder combinations: 1) GBS as the only binder; 2) blended binder with a slag-to-fly ash ratio of 3:1; and 3) mixed binder with 1:1 ratio of slag to fly ash. Mortar samples were mixed and cured at (22 ± 2) °C till the day of the test. The impact of activator solution alkalinity, activator ratio Na2SiO3/NaOH, GBS content on the rate of water absorption were evaluated. After 7, 28, and 90 d of immersion in a 10% sulfuric acid solution, the resistance of a geopolymer matrix to degradation was assessed by measuring the change in sample weight. The influence of solution alkalinity and relative fly ash content on setting times was investigated. Alkali-activated mortar with a slag-to-fly ash ratio of 3:1 had the least sorptivity compared to the two other binder combinations, at each curing age, and for mortars made with each of the NaOH alkaline activator concentrations. Mortar sorptivity decreased with age and sodium hydroxide concentrations, suggesting the production of geopolymerization products. No reduction in weight of sample occurred after immersion in the strong acid H2SO4 solution for three months, regardless of binder combination. This was due to the synthesis of hydration and geopolymerization products in the presence of curing water, which outweighed the degradation of the geopolymer matrix caused by sulfuric acid.

Keywords: materials     fly ash     sorptivity     durability of concrete     sodium hydroxide     sodium silicates     reduction in CO    

comparison of the catalytic hydrogenation of 2-amylanthraquinone and 2-ethylanthraquinone over a Pd/Al

Enxian Yuan, Xiangwei Ren, Li Wang, Wentao Zhao

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 2,   Pages 177-184 doi: 10.1007/s11705-016-1604-0

Abstract: ratios of 1:1 and 1:2 to the corresponding hydroquinones (eAQH and taAQH ) were studied over a Pd/AlO catalyst in a semi-batch slurry reactor at 60 °C and at 0.3 MPa.in taAQ, which limits its accessibility to the Pd surface and its diffusion through the pores of the catalyst

Keywords: hydrogenation     hydrogen peroxide     anthraquinone     Pd catalyst     AO process    

A mini review on chemical fixation of CO 2 : Absorption and catalytic conversion into cyclic carbonates

Weili DAI, Chaktong AU, Shenglian LUO, Shuangfeng YIN,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 2,   Pages 163-171 doi: 10.1007/s11705-009-0235-0

Abstract: We fabricated bismuth biphenoate complex, Zn-Mg-Al composite oxides, and SBA-15 or Al-SBA-15 immobilizedhydroxyl ionic liquid for CO cycloaddition onto epoxides.The hypervalent bismuth compounds show good ability for association and dissociation with CO.Zn-Mg-Al oxides and SBA-15 or Al-SBA-15 immobilized ionic liquid, are efficient for the synthesis ofcyclic carbonate from CO and epoxide.

Keywords: SBA-15     CO cycloaddition     Al-SBA-15 immobilized     CO     dissociation    

Al2O3 and CeO2-promoted MgO sorbents for CO2 capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 83-93 doi: 10.1007/s11705-017-1691-6

Abstract: A series of Al O and CeO modified MgO sorbents was prepared and studied for CO sorption at moderateThe CO sorption capacity of MgO was enhanced with the addition of either Al O or CeO .Over Al O -MgO sorbents, the best capacity of 24.6 mg-CO /g-sorbent was attained at 100 °C, which wascapacity than Al O promoter.Compared to Al O , CeO is more effective for promoting the CO capacity of MgO.

Keywords: CO2 capture     MgO sorbents     Al2O3     CeO2     flue gas    

Fe - Ni - Co - Al2O3 Cermets Inert Anode for Aluminum Electrolysis

Qiu Zhuxian,Shi Zhongning,Xu Junli

Strategic Study of CAE 2004, Volume 6, Issue 8,   Pages 35-39

Abstract: The cell was built with a graphite cathode of 120 mm×40 mm×20 mm and a Fe - Ni - Co -AlCo.confirmed that the electrochemical reaction occurred in the electrolysis cell was the decomposition of Al

Keywords: aluminum electrolysis     inert anode     back EMF value    

Title Author Date Type Operation

Gas phase ethylene polymerization over SiO

Liuzhong LI, Aiyou HAO, Ruihua CHENG, Boping LIU

Journal Article

Dendritic BiVO4 decorated with MnOx co-catalyst as an efficient hierarchical catalyst for photocatalytic

Jin Yang, Xuelian Liu, Hongbin Cao, Yanchun Shi, Yongbing Xie, Jiadong Xiao

Journal Article

Mass Transfer-Promoted Fe2+/Fe3+ Circulation Steered by 3D Flow-Through Co-Catalyst System Toward Sustainable

Weiyang Lv,Hao Li,Jinhui Wang,Lixin Wang,Zenglong Wu,Yuge Wang,Wenkai Song,Wenkai Cheng,Yuyuan Yao,

Journal Article

Improved Oxygen Evolution Kinetics and Surface States Passivation of Ni-Bi Co-Catalyst for

Ke Dang,Tuo Wang,Chengcheng Li,Jijie Zhang,Shanshan Liu,Jinlong Gong

Journal Article

Effect of alkyl nitrite decomposition on catalytic performance of CO coupling reaction over supportedpalladium catalyst

Zhenhua LI, Weihan WANG, Dongxue YIN, Jing LV, Xinbin MA

Journal Article

Ni-Co bimetallic catalyst for CH

Xiaohong LI, Jun AI, Wenying LI, Dongxiong LI

Journal Article

The stabilization effect of Al2O3 on unconventional Pb/SiO2 catalyst

Journal Article

CO2 methanation and co-methanation of CO and CO2 over Mn-promoted Ni/Al2

Kechao Zhao,Zhenhua Li,Li Bian

Journal Article

The catalytic effect of both oxygen-bearing functional group and ash in carbonaceous catalyst on CH 4-CO 2 reforming

Weidong ZHANG, Yongfa ZHANG,

Journal Article

Resistance to acid degradation, sorptivity, and setting time of geopolymer mortars

Osama A MOHAMED; Rania AL-KHATTAB; Waddah AL-HAWAT

Journal Article

comparison of the catalytic hydrogenation of 2-amylanthraquinone and 2-ethylanthraquinone over a Pd/Al

Enxian Yuan, Xiangwei Ren, Li Wang, Wentao Zhao

Journal Article

A mini review on chemical fixation of CO 2 : Absorption and catalytic conversion into cyclic carbonates

Weili DAI, Chaktong AU, Shenglian LUO, Shuangfeng YIN,

Journal Article

Chen Yiran: Hardware/Software Co-design for Al Systems (2020-5-16)

19 Apr 2022

Conference Videos

Al2O3 and CeO2-promoted MgO sorbents for CO2 capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Journal Article

Fe - Ni - Co - Al2O3 Cermets Inert Anode for Aluminum Electrolysis

Qiu Zhuxian,Shi Zhongning,Xu Junli

Journal Article